Colourless crystals of the title compound, [Ag(C5H7N3)(C6H9N3)]NO3, separated out of a solution of 2-amino-4-methylpyrimidine, 2-amino-4,6-dimethylpyrimidine and silver nitrate in water and methanol. The central AgI ion is coordinated by two different N atoms in the aromatic rings of the ligands, with an N—Ag—N angle of 173.9 (2)°. The crystal structure is composed of two complexed cations and stabilized by an intermolecular N—H...O and N—H...N hydrogen-bond network and there is π–π stacking of the aromatic rings [interplanar distance 3.651 (10) Å].

+More

amp960amp8211amp960 stacking namp8212ho and namp8212hn hydrogenbond network

Hua Yang,.(2-Amino-4,6-dimethylpyrimidine-κN1)(2-amino-4-methylpyrimidine-κN1)silver(I) nitrate. 65 (10),.

Hua Yang,"(2-Amino-4,6-dimethylpyrimidine-κN1)(2-amino-4-methylpyrimidine-κN1)silver(I) nitrate" 65

Hua Yang,"(2-Amino-4,6-dimethylpyrimidine-κN1)(2-amino-4-methylpyrimidine-κN1)silver(I) nitrate"