Welcome to the IKCEST

Mass Spectrometry Letters | Vol.3, Issue.2 | 2017-06-09 | Pages

Mass Spectrometry Letters

Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel

Arif Ahmed,Sunghwan Kim,Yunju Cho,Annana Islam  
Abstract

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples

Original Text (This is the original text for your reference.)

Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples

+More

Cite this article
APA

APA

MLA

Chicago

Arif Ahmed,Sunghwan Kim,Yunju Cho,Annana Islam,.Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel. 3 (2),.

References

Disclaimer: The translated content is provided by third-party translation service providers, and IKCEST shall not assume any responsibility for the accuracy and legality of the content.
Translate engine
Article's language
English
中文
Pусск
Français
Español
العربية
Português
Kikongo
Dutch
kiswahili
هَوُسَ
IsiZulu
Action
Recommended articles

Report

Select your report category*



Reason*



By pressing send, your feedback will be used to improve IKCEST. Your privacy will be protected.

Submit
Cancel