Mass Spectrometry Letters | Vol.3, Issue.2 | 2017-06-09 | Pages
Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel
In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples
Original Text (This is the original text for your reference.)
Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel
In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotronresonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have beencombined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturatedcyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with morethan two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings wereidentified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compoundswere observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICRMS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each otherfor more complete understanding of oil samples
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alkyl saturatedcyclic appi fticr dimension gas chromatography 2d gcms chemical atmospheric pressure photo ionization cyclic ring 15 t fourier transform ion cyclotronresonance mass spectrometry 15t fticr 15t fticrms
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Arif Ahmed,Sunghwan Kim,Yunju Cho,Annana Islam,.Application of comprehensive 2D GC-MS and APPI FT-ICR MS for more complete understanding of chemicals in diesel fuel. 3 (2),.
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