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Prikladnaia biokhimiia i mikrobiologiia | Vol.44, Issue.3 | | Pages 296-303

Prikladnaia biokhimiia i mikrobiologiia

[Micellar laccase-catalyzed synthesis of electroconductive polyaniline].

A V, Strel'tsov G P, Shumakovich O V, Morozova M A, Gorbacheva A I, Iaropolov  
Abstract

A method of enzymatic synthesis of electroconductive polyaniline on the micelles of dodecylben-zenesulfonic acid sodium salt (DBSNa) is proposed. The high potential laccase from the basidiomycete Trametes hirsuta was used as a biocatalyst. The conditions for polyaniline synthesis were optimized (pH 4.0; reagent concentrations, 10-20 mM; and aniline/DBSNa ratio, 2: 1). The resulting product was electrochemically active in the range of potentials from -200 to 600 mV, electroconductive, and capable of reversible dedoping with a change in pH of solution.

Original Text (This is the original text for your reference.)

[Micellar laccase-catalyzed synthesis of electroconductive polyaniline].

A method of enzymatic synthesis of electroconductive polyaniline on the micelles of dodecylben-zenesulfonic acid sodium salt (DBSNa) is proposed. The high potential laccase from the basidiomycete Trametes hirsuta was used as a biocatalyst. The conditions for polyaniline synthesis were optimized (pH 4.0; reagent concentrations, 10-20 mM; and aniline/DBSNa ratio, 2: 1). The resulting product was electrochemically active in the range of potentials from -200 to 600 mV, electroconductive, and capable of reversible dedoping with a change in pH of solution.

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A V, Strel'tsov G P, Shumakovich O V, Morozova M A, Gorbacheva A I, Iaropolov,.[Micellar laccase-catalyzed synthesis of electroconductive polyaniline].. 44 (3),296-303.

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